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Raman spectroscopy has also been successfully used to determine the organic component of ancient stone and paintings, such as the paintings on the Dark Room frescoes from Pompeii. Specifically, Raman spectroscopy was used to measure the ratio of proteins to carbohydrates in the surface of the ancient fresco, which was found to be similar to the human skin of their creators, thus providing important forensic evidence to help solve the mystery of who painted the frescoes. This type of spectroscopy has also been used to help determine the authenticity of ancient sculptures and paintings. For example, Raman spectroscopy was used to evaluate the depth and chemical composition of the paint layer on the Buddha at the Bamiyan caves. These results were then compared to the composition of paint that was found on the sculptures in the caves, which were considered to be authentic. See the Buddha at the Bamiyan caves Buddhism in Kazakhstan .
Raman spectroscopy has been used to examine the authenticity of important works of art and cultural heritage artifacts, such as paintings and pottery. For example, some asian cultures have used the pits and grooves in the rims of ancient vases as a form of authentication. The rims have grooves and pits that are chemically and structurally distinct from the body of the vase. Raman spectroscopy was used to analyze the chemical composition of the grooves and pits of such vases, showing that the pits had almost the same chemical composition as the body of the vase (thereby confirming their authenticity), whereas the grooves had different chemical composition. This was found to be a useful way to authenticate ancient artifacts, even if they suffered from surface abrasion.
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